TRANS-二(氰基苯)二氯合钯 (II) *
Bis(benzonitrile)palladium(II) chloride
CAS: 14220-64-5
Molecular Formula: C14H10Cl2N2Pd
TRANS-二(氰基苯)二氯合钯 (II) * - Names and Identifiers
| Name | Bis(benzonitrile)palladium(II) chloride |
| Synonyms | Pd(PhCN)2Cl2 Benzonitrile, palladium complex Dibenzonitrilepalladium dichloride Bis(benzonitrile)palladium chloride Bis(phenylnitrile)dichloropalladium Dichlorobis(benzonitrile)palladium(Ⅱ) Bis(benzonitrile)dichloropalladium ii Bis(Benzonitrile)Dichloropalladium(II) Bis(benzonitrile)palladium(II)chloride Dichlorobis(benzonitrile)palladium(II) Bis(benzonitrile)palladium(II) chloride trans-Bis(benzonitrile)palladiuM chloride TRANS-BIS-(BENZONITRILE)PALLADIUM(II) CHLORIDE |
| CAS | 14220-64-5 |
| EINECS | 238-085-3 |
| InChI | InChI=1/2C7H5N.2ClH.Pd/c2*8-6-7-4-2-1-3-5-7;;;/h2*1-5H;2*1H;/q;;;;+2/p-2 |
| InChIKey | WXNOJTUTEXAZLD-UHFFFAOYSA-L |
TRANS-二(氰基苯)二氯合钯 (II) * - Physico-chemical Properties
| Molecular Formula | C14H10Cl2N2Pd |
| Molar Mass | 383.57 |
| Melting Point | 131°C(lit.) |
| Boling Point | 191.1°C at 760 mmHg |
| Flash Point | 71.7°C |
| Water Solubility | insoluble |
| Solubility | Soluble in acetone, chloroform |
| Vapor Presure | 0.524mmHg at 25°C |
| Appearance | Yellow to orange or brown powder |
| Color | Orange to brown |
| Exposure Limit | NIOSH: IDLH 25 mg/m3 |
| BRN | 3981730 |
| Storage Condition | Inert atmosphere,2-8°C |
| Sensitive | 4: no reaction with water under neutral conditions |
| MDL | MFCD00013123 |
TRANS-二(氰基苯)二氯合钯 (II) * - Risk and Safety
| Hazard Symbols | Xn - Harmful |
| Risk Codes | R20/21 - Harmful by inhalation and in contact with skin. R23/24/25 - Toxic by inhalation, in contact with skin and if swallowed. |
| Safety Description | S22 - Do not breathe dust. S24/25 - Avoid contact with skin and eyes. S23 - Do not breathe vapour. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) S36/37 - Wear suitable protective clothing and gloves. S27 - Take off immediately all contaminated clothing. S20 - When using, do not eat or drink. S9 - Keep container in a well-ventilated place. S4 - Keep away from living quarters. |
| UN IDs | UN3439 |
| WGK Germany | 3 |
| FLUKA BRAND F CODES | 9 |
| TSCA | No |
| HS Code | 28439090 |
| Hazard Class | 6.1 |
| Packing Group | III |
TRANS-二(氰基苯)二氯合钯 (II) * - Reference Information
| Preparation | Bis (cyanobenzene) palladium dichloride can be prepared by reacting palladium acetate or palladium chloride with benzonitrile. A mixture of palladium (II) acetate (502 mg,2.2 mmol),HCl(37% aqueous solution, 0.7 mL,8.5 mmol) and benzonitrile (15 mL) was stirred for 30 minutes in a 50 mL flask at 90°C. Let the mixture cool at 20°C, and then add hexane (8 mL). The mixture was filtered through diatomite and washed with hexane. The filtrate was cooled to 4°C to obtain crystals. Filter crystals. Wash with hexane and dry under high vacuum. |
| use | palladium bis (cyanobenzene) dichloride is a palladium catalyst, which is widely used in the fields of organic chemical industry, pharmaceutical chemical industry and liquid crystal material synthesis. Chinese alias bis (benzonitrile) palladium chloride, reverse bis (benzonitrile) dichloropalladium (II), yellow powder, insoluble in water, soluble in acetone and chloroform. Store in a closed and dry place. |
Last Update：2024-04-09 20:49:11
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View History
TRANS-二(氰基苯)二氯合钯 (II) *
磷腈配体 P4-叔丁基 四氟硼酸盐
2-甲氧基-3-醛基苯硼酸
丙基三(三甲基硅氧基)硅烷
2-氯-6-苄基氨基-7-甲基嘌呤
3-[4-硼酸频哪醇酯]苯基]吡啶
苯并[d]异噁唑-5-磺酰氯
[3-(4-Morpholinyl)propyl]dithiocarbamic acid
TETRAISOPROPYL 1,2-ETHYLENEDIPHOSPHONATE
4-羧基-3-硝基苯硼酸
磷腈配体 P4-叔丁基 四氟硼酸盐
2-甲氧基-3-醛基苯硼酸
丙基三(三甲基硅氧基)硅烷
2-氯-6-苄基氨基-7-甲基嘌呤
3-[4-硼酸频哪醇酯]苯基]吡啶
苯并[d]异噁唑-5-磺酰氯
[3-(4-Morpholinyl)propyl]dithiocarbamic acid
TETRAISOPROPYL 1,2-ETHYLENEDIPHOSPHONATE
4-羧基-3-硝基苯硼酸